A reddit user has posted a list of PS3 games that work with the DUALSHOCK 4 controller.
Obviously this is not a full list of games since this is based on the user’s own personal collection of PS3 games. Still, there are a number off games that work with the DUALSHOCK 4 controller, while some games don’t.
He posted some instructions to use the DUALSHOCK 4 on PS3 too. The controller works only being connected via a cable to the PS3 (no wireless). Also, “Vibration, Motion Sensing, and the Playstation Button do NOT work“. The share/options buttons are equivalent to the start/select buttons.
Check out the list of PS3 games (so far) that work with the DUALSHOCK 4 controller:
Working
PS1 Games
Call of Duty (MW2, MW3, Black Ops, Black Ops 2)
Castle Crashers
Portal 2
Far Cry 2
The Last of Us
LittleBigPlanet/LittleBigPlanet 2
Ni No Kuni: Wrath of the White Witch
Heavy Rain (no motion sensing)
Uncharted 1/2/3
Red Dead Redemption
Infamous + Infamous 2
Resistance 2 (had to use a DS3 to get past the start screen, but DS4 worked fine after that)
Killzone 3
Dead Space
Battlefield: Bad Company 2
Motorstorm (Apocalypse, Pacific Rift)
Tomb Raider
Prototype
Skyrim
Dark Souls
Battlefield 3
Far Cry 3: Blood Dragon
Final Fantasy XIV
Super Stardust HD
Diablo 3
Bioshock: Infinite
Kingdom Hearts 1.5 HDNot Working
Grand Theft Auto V
Resistance 3
Jak and Daxter HD Collection (only the analog sticks work)
Gran Turismo 5